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Volume : III, Issue : IV, May - 2013

2-PENTANENITRILE - CHLOROBENZENE MOLECULAR INTERACTION STRENGTH AT 450C TEMPERATURE USING TIME DOMAIN TECHNIQUE

SHERE ISHWAR GURUNATHRAO

Published By : Laxmi Book Publication

Abstract :

The dielectric spectra of 2-pentanenitrile (PN) and chlorobenzene (CBZ) binary mixtures have been studied by using the time domain reflectometry (TDR) at 450C temperature. The frequency range used for the study has been 10 MHz to 20 GHz. The system has been studied for 11 different concentrations. The dielectric parameters have been obtained by Fourier transform and the least squares fit method. These parameters are fitted in Kirkwood and Bruggeman model. The Kirkwood correlation factor (gf) and effective Kirkwood correlation factor (geff) of the mixtures have been determined by fitting static dielectric constant in the Kirkwood model. Similarly, Bruggeman parameters are also obtained. In the mixtures the values of geff are less than one and it shows that; the antiparallel alignment of dipoles. The values of gf are more deviated from one for all concentrations of the system it indicates stronger interaction between the constituent molecules of the system. The strong interaction between the constituent molecules in this system confirms by Bruggeman result.

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SHERE ISHWAR GURUNATHRAO, (2013). 2-PENTANENITRILE - CHLOROBENZENE MOLECULAR INTERACTION STRENGTH AT 450C TEMPERATURE USING TIME DOMAIN TECHNIQUE. Indian Streams Research Journal, Vol. III, Issue. IV, http://oldisrj.lbp.world/UploadedData/2422.pdf

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