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Volume : V, Issue : VII, August - 2015

TEMPERATURE DEPENDENT DIELECTRIC RELAXATION STUDY OF ETHANOL-N N DIMETHYL FORMAMIDE BINARY MIXTURE AT GIGA HERTZ FREQUENCY RANGE.

Patil H. T., Shivalkar K.N.

By : Laxmi Book Publication

Abstract :

Dielectric Behavior of N,N-Dimethyl Acetamide [CH3CON(CH3)2] – Ethanol [C2H5OH] binary mixture at different temperatures 15, 25, 35 and 450c have been determined over frequency range of 10 MHz to 20 GHz. Using the Time Domain Reflectometry Technique in reflection mode for 11 different concentrations of given binary system has been used to measure reflection coefficient. Further Fourier transform and least square fit method have been used to obtain dielectric parameters such as dielectric constant (ε0) and relaxation time (τ). The dielectric constant decreased with an increase in temperature where as it increased with increase in concentration. Relaxation time decreased with an increase in temperature and concentration. By using dielectric parameters excess permittivity (εE), excess inverse relaxation time (1/τ)E and Kirkwood factor (g) and (geff) has been worked out.

Keywords :


    Article :


    Cite This Article :

    Patil H. T., Shivalkar K.N.(2015). TEMPERATURE DEPENDENT DIELECTRIC RELAXATION STUDY OF ETHANOL-N N DIMETHYL FORMAMIDE BINARY MIXTURE AT GIGA HERTZ FREQUENCY RANGE.. Indian Streams Research Journal, Vol. V, Issue. VII, http://isrj.org/UploadedData/7041.pdf

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    138. Cole R H, J G Berbarian, S Mahimo, G Chryssikos, A. Burns. And E.Tombouri. J. Appl.phy; 66, (1989) 793-802.
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    140. Ajay chaudhari, Anita Das, Gargipati Raju, Harish chaudhari, prakash khirade, Navinkumar Naraian and Suresh mehrotra, Proc. Nati. Sci. counc. Roc (A) vol 25, No.4, 2001 PP.205-210.
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    144. Cole R H, J G Berbarian, S Mahimo, G Chryssikos, A. Burns. And E.Tombouri. J. Appl.phy; 66, (1989) 793-802.
    145. Shanon CE Proc. IRE(1949) 37,10
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    147. Aajay Chaudhari, M.K.Lande, B.R.Arbad, D.V.Jahagirdar and S.C.Mehrotra. J. Mole. Liquids 100/3.(2002) 207-215.
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    156. Shanon CE Proc. IRE(1949) 37,10
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    170. P.W. Khirade, Aajay Chaudhari, J.B Shinde, S.N. Helambe and S.C. Mehrotra. J.chem.Eng. Data 1999, 44, 879-881.
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    173. Aajay Chaudhari, M.K.Lande, B.R.Arbad, D.V.Jahagirdar and S.C.Mehrotra. J. Mole. Liquids 100/3.(2002) 207-215.
    174. Ajay chaudhari, Anita Das, Gargipati Raju, Harish chaudhari, prakash khirade, Navinkumar Naraian and Suresh mehrotra, Proc. Nati. Sci. counc. Roc (A) vol 25, No.4, 2001 PP.205-210.
    175. Shamulan H A. IRE (1951), 39, 175-183.
    176. Ajay chaudhari, N.M.More,and S.C Mehrotra, Bull Korean chem. Soc. 2001;vol.22, No 4, 357-361
    177. Cole R H, J G Berbarian, S Mahimo, G Chryssikos, A. Burns. And E.Tombouri. J. Appl.phy; 66, (1989) 793-802.
    178. Shanon CE Proc. IRE(1949) 37,10
    179. Haverliak and Nigami. J. polym. sci. (1966), polym. Symp; 6, 99-117.
    180. Haverliak and Nigami. J. polym. sci. (1966), polym. Symp; 6, 99-117.
    181. Cole R H, J G Berbarian, S Mahimo, G Chryssikos, A. Burns. And E.Tombouri. J. Appl.phy; 66, (1989) 793-802.
    182. Shanon CE Proc. IRE(1949) 37,10
    183. P.W. Khirade, Aajay Chaudhari, J.B Shinde, S.N. Helambe and S.C. Mehrotra. J.chem.Eng. Data 1999, 44, 879-881.
    184. Ajay chaudhari, G.S. Raju, Anita Das, Harish chaudhari, N.K.Naraian and Suresh mehrotra, Ind.J.of pure and applied physics vol.39,march 2001; pp 180-183.
    185. V.P Pawar and S.C Mehrotra. Bulletin of pure and appl. Sci. Vol.20D(No.1)2001; p. 9-16
    186. Aajay Chaudhari, M.K.Lande, B.R.Arbad, D.V.Jahagirdar and S.C.Mehrotra. J. Mole. Liquids 100/3.(2002) 207-215.
    187. Ajay chaudhari, N.M.More,and S.C Mehrotra, Bull Korean chem. Soc. 2001;vol.22, No 4, 357-361
    188. Ajay chaudhari, N.M.More,and S.C Mehrotra, Bull Korean chem. Soc. 2001;vol.22, No 4, 357-361
    189. Ajay chaudhari, G.S. Raju, Anita Das, Harish chaudhari, N.K.Naraian and Suresh mehrotra, Ind.J.of pure and applied physics vol.39,march 2001; pp 180-183.
    190. Haverliak and Nigami. J. polym. sci. (1966), polym. Symp; 6, 99-117.
    191. P.W. Khirade, Aajay Chaudhari, J.B Shinde, S.N. Helambe and S.C. Mehrotra. J.chem.Eng. Data 1999, 44, 879-881.
    192. Ajay chaudhari, Anita Das, Gargipati Raju, Harish chaudhari, prakash khirade, Navinkumar Naraian and Suresh mehrotra, Proc. Nati. Sci. counc. Roc (A) vol 25, No.4, 2001 PP.205-210.
    193. Shamulan H A. IRE (1951), 39, 175-183.
    194. Ajay chaudhari, G.S. Raju, Anita Das, Harish chaudhari, N.K.Naraian and Suresh mehrotra, Ind.J.of pure and applied physics vol.39,march 2001; pp 180-183.
    195. Cole R H, J G Berbarian, S Mahimo, G Chryssikos, A. Burns. And E.Tombouri. J. Appl.phy; 66, (1989) 793-802.
    196. Shanon CE Proc. IRE(1949) 37,10
    197. Haverliak and Nigami. J. polym. sci. (1966), polym. Symp; 6, 99-117.
    198. Haverliak and Nigami. J. polym. sci. (1966), polym. Symp; 6, 99-117.
    199. P.W. Khirade, Aajay Chaudhari, J.B Shinde, S.N. Helambe and S.C. Mehrotra. J.chem.Eng. Data 1999, 44, 879-881.
    200. Haverliak and Nigami. J. polym. sci. (1966), polym. Symp; 6, 99-117.
    201. Ajay chaudhari, Anita Das, Gargipati Raju, Harish chaudhari, prakash khirade, Navinkumar Naraian and Suresh mehrotra, Proc. Nati. Sci. counc. Roc (A) vol 25, No.4, 2001 PP.205-210.
    202. Shamulan H A. IRE (1951), 39, 175-183.
    203. Ajay chaudhari, N.M.More,and S.C Mehrotra, Bull Korean chem. Soc. 2001;vol.22, No 4, 357-361
    204. Ajay chaudhari, G.S. Raju, Anita Das, Harish chaudhari, N.K.Naraian and Suresh mehrotra, Ind.J.of pure and applied physics vol.39,march 2001; pp 180-183.
    205. Cole R H, J G Berbarian, S Mahimo, G Chryssikos, A. Burns. And E.Tombouri. J. Appl.phy; 66, (1989) 793-802.
    206. Shanon CE Proc. IRE(1949) 37,10
    207. V.P Pawar and S.C Mehrotra. Bulletin of pure and appl. Sci. Vol.20D(No.1)2001; p. 9-16
    208. Aajay Chaudhari, M.K.Lande, B.R.Arbad, D.V.Jahagirdar and S.C.Mehrotra. J. Mole. Liquids 100/3.(2002) 207-215.

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