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Volume : II, Issue : VIII, September - 2012 Synthesis Of Schiff's Base Ligands By Condensation Of 2-hydroxyacetophenone And Chiral Diamines Manoj Kumar Agrawala , Manish Kaushik , Amit Singhalc DOI : 10.9780/22307850, Published By : Laxmi Book Publication Abstract : Three optically active Schiff-base ligands 2-4 have been prepared by thermal
condensation of 2-hydroxyacetophenone 1 with (1R,2R)-(-)-1,2-diaminocyclohexane,
(1S,2S)-(-)- 1,2-diphenylethylenediamine or R-(+)-2,2'-diamino-1,1'-binaphthalene,
respectively. The products have been characterized by their elemental analysis, IR, 1HNMR
spectra. Keywords : Article : Cite This Article : Manoj Kumar Agrawala , Manish Kaushik , Amit Singhalc, (2012). Synthesis Of Schiff's Base Ligands By Condensation Of 2-hydroxyacetophenone And Chiral Diamines. Indian Streams Research Journal, Vol. II, Issue. VIII, DOI : 10.9780/22307850, http://oldisrj.lbp.world/UploadedData/1373.pdf References : - (a) Zhang, J.X.; Zhou, Y.; Cai, G. Preparation of Schiff base-Cu complex and their application in the asymmetric synthesis of chrysanthemate, J. Mol. Catal (China), 1997, 11, 41-44; (b) Holland, D; Laidler, D.A.; Milner, D.J. Catalytic asymmetric synthesis of cyclopropane carboxylates: Ligandreagent interaction in diazoacetate reactions catalysed by copper(II)species bearing sugar-Schiff base ligands, J. Mol. Catal., 1981, 11,119-127; (c) Chen, G.M.; Chen, F.; Zhou, C.. Synthesis of chiral copper(II) compounds and their application in asymmetric cyclopropanation of olefins, Chem. J. Chin. Univ., 1995, 16, 216-219; (d) Qiu, M.; Liu, G.; Yiao, X. Chiral copper (II)-Schiff base complexes as catalysts for asymmetric cyclopropanation of styrene, Chin. J. Catal., 2001, 22, 77-80; (e) Li, C.; Zhang, W.; Yao, X. Synthesis of a new C2-symmetric chiral Schiff base and its catalytic performance in asymmetric cyclopropanation, Chin. J. Catal., 2000, 21, 77-80; (f) Li, Z.N.; Liu, G.; Zheng, Z. Asymmetric cyclopropanation of styrene catalyzed by Cu-(chiral Schiff-base) complexes, Tetrahedron, 2000, 56, 7187- 7191.
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